Phys 408: Statistical Physics

Instructor:                                                                                

Gabe Spalding C006B CNS
Office hours:
T 10:00 - 11:50am, 1:00 - 1:50pm
Th 11:00 - 11:50am
F 2:00 - 2:50pm
gspalding@titan.iwu.edu
556-3004
E-mail is always welcome.


Outline: (A tentative Schedule is included below)

Room E101, Official class meeting hours = MF: 11:00 am - 12:15 pm, W: 9:00 - 9:50 am

Primary Texts: An Introduction to Thermal Physics, by Daniel V. Schroeder (see the author's website)

Thermal Physics, by Ralph Baierlein

Supplementary Texts: Your texts from Physics I, Physics II, and (especially) Physics III !!!

(You must have these texts on your shelf when you read the texts for this course!)


Additional References Include:

Physical Chemistry, by P. W. Atkins (on RESERVE in the library)

Understanding the Properties of Matter, by Michael de Podesta (on RESERVE in the library)

Mathematica will be used on a semi-regular basis in homework assignments; however, no previous Mathematica experience will be required.


While the primary texts supply us with a reliable structure for the course (i.e., we will follow them closely), it is my hope that we will all work together to enhance what these primary references present, with the goal of helping one another identify and develop personal interests. Please come to the course meetings prepared for lively discussion.

The Big Picture:


#1 Requirement: Keep up with the reading

Complete the Reading for each Chapter before discussion begins in class

To each class meeting, you are expected to bring a "status sheet". This is simply a list of (three or so) questions you have regarding the material to be covered in class. I want you to really analyze whether or not you understand the reading. The depth of your considerations, as reflected in your status sheets and in your classroom participation, will account for 10% of your final course grade.

If the material in your primary text is not clear at any point, it is your responsibility to seek out clarifying materials (primarily from your Intro Physics text) and to share insights with the rest of the class during our meetings.

Grading:


Tentative Schedule

Problems of the Week

Date

Lecture Topic

Reading Assignment
(To be read in
preparation for lecture)

Note of the Week

HW Set#1 Due W: 1.7(a), 1.8, 1.16;

HW Set#2 Due F: 1.17, 1.20,
1.22 (a, b, c, e - give radius),
1.34;

HW Set#3 Due M: 2.4, 2.5, 2.6

Mon, Aug. 22

What is Statistical Physics?

Modern Phys. Text (Thornton & Rex) Ch. 9

Wed, Aug. 24

Thermal Equilibrium;
Microscopic Model of the Ideal Gas;
Equipartition Theorem;
Heat and Work

Through p. 20 of DS (i.e., Daniel Schroeder); Supplement with Ch 1 of B (i.e., Baierlein)

Fri, Aug. 26

Compressive Work;
Heat Capacities;
Your questions about Latent Heat & Enthalpy;
Your questions about Rates of Processes

Through p. 48 of DS

Review the Appendix in Thornton & Rex on "Mean Values and Distributions" (and find the typo), and at least look through the Math Appendix in DS.

Ch 2:
HW Set# 4 Due W: B2.3 and DS# 2.8, 2.11, 2.16

HW Set# 5 Due F: B2.8 and DS# 2.17, 2.18, 2.22;

HW Set# 6 Due M: Read!

Mon, Aug. 29

Moving towards the Second Law:
Two-State Systems (Coins & Simplest Paramagnets);
Einstein Model of a Solid (An array of Quantum Oscillators)

DS Ch. 2, p. 49-55

Wed, Aug. 31

Review of DS p. 55;
Boltzmann & the Ergodic Hypothesis;
The beauty (and challenge) of very large numbers

DS Ch. 2, p. 56-67 (bottom); supplement with p. 24-27 of B (i.e., Baierlein)

Fri, Sept. 2

At long last, ENTROPY!

Pick up Take-Home EXAM!

Slog through DS Ch. 2, p. 68-84; then appreciate p. 28-46 of B

For Monday: Stochasticity,

For Wednesday: the Ergodic Hypothesis, and
testing the Ergodic theorem

For Friday: Entropic Crystallization

HW Set# 7 Due W: DS # 2.19, 2.21, 2.29, 2.31;

HW Set# 8 Due F: DS # 2.33, 2.35, 2.37,

HW Set# 9 Due M: DS # 2.34 Parts (a) and (b)

Sept. 5

No Class! (Work on EXAMINATION I, which covers through DS Sect. 2.4)

Ch. 2

Sept. 7

Segue from DS Ch 2 to DS Ch3;
Baierlein's "desert"

DS Sect. 3.1

Sept. 9

Connections between "micro" and "macro": thinking about temperature

DS Sect. 3.2

For Wednesday:
Entropy and Temperature

HW Set# 10 Due W: DS # 3.24
HW Set# 11 Due F: Individ. Problems
HW Set# 12 Due M: DS # 3.37

Sept. 12

DILUTE Paramagnetism:
Entropy is more fundamental than temperature!

DS Sect. 3.3

Sept. 14

A new view of Pressure

DS Sect 3.4

Sept. 16

Chemical Potential

DS Sect. 3.5 and 3.6

For Monday:
Negative Temperature, Dilute Paramagnet Blurb of the Week, Getting colder than you can imagine. And then even colder.

For Wednesday:
Thinking about Pressure and equilibrium

For Friday:
Chemical Potential

HW Set# 13 Due W: Catch up!
HW Set# 14 Due F: Catch up!
HW Set# 15 Due M: DS # 4.21

Sept. 19

EXAMINATION II covers through DS Ch. 3

Review!

Sept. 21

Review!

Review!

Sept. 23

Heat Engines

Start DS Ch. 4, supplement with B Ch. 3

For Friday:
Stirling Cycle Details, "Super-Soakers" and Heat Engines

HW Set# 16 Due W: DS # 4.16, 4.17

HW Set# 17 Due F: Read DS Sect. 5.1 - 5.2,
B Sect. 10.1-2, 10.4, 10.7

HW Set# 18 Due M: DS # 5.8, 5.9

Sept. 26

Heat Engines & Refrigerators

B Ch. 3, supplement with DS Ch. 4

Sept. 28

Gibbs Free Energy & Phase Transitions

Start DS Ch 5

Sept. 30

Thermodynamic Identities & Maxwell Relations;
Free Energy as a Drive toward Equilibrium:
  Critical Droplet Size

DS Sect. 5.1-5.2,
with B Sect 10.1-10.2, 10.4, 10.7

Review text regarding:
Fig 1.15 (on p. 33),
Fig. 5.1 (on p. 150), and
Fig. 5.9 (on p. 163)

HW Set# 19 Due W: DS # 5.15, 5.46

HW Set# 20 Due F: DS # 5.36

HW Set# 21 Due M: Read DS Sect 5.4

Oct. 3

Phase Equilibrium:
Clausius-Clapeyron,
Gibbs Phase Rule

DS Sect. 5.3;

Oct. 5

Phase Transitions & Reduced Variables

B, Ch 12 (omitting "A model for the vaporization curve" on pages 276-278 and "SOLID Helium-3" on page 283)

Oct. 7

Order Parameters and Critical Exponents

Critical Exponents

Helium-3 Phase Transitions

HW Set# 22 Due W: DS # 5.62

HW Set# 23 Due F: Start reading DS Ch 6!

HW Set# 24 Due M: DS # 6.11, 6.12

Oct. 10

Phase Transformations of Mixtures:
Ideal Mixing of a Miscible Mixture;
Eutectics;
Intermetallics

Review DS p. 79-81;
DS Sect. 5.4

Oct 12

Osmotic Pressure

DS Sect. 5.5

Oct. 14

No Class!

READ!

DS Sect. 6.1-6.2

Critical Exponents,
Order Parameters,
Universality Classes

HW Set# 25 Due W: DS # 6.16;

HW Set# 26 Due F: DS # 6.22

HW Set# 27 Due M: DS # 6.44, 6.46

Oct. 17

Boltzmann Stats:
Boltzmann Factor
Partition Function(!)

DS Sect. 6.1-6.2; Baierlein, Ch 5

Oct. 19

Still More Boltzmann Stats:
Still More Boltzmann Factor
Still More Partition Function(!)

Remainder of DS Ch 6

Oct. 21

Even More Boltzmann Stats:
Even More Boltzmann Factor
Even More Partition Function(!)

DS Ch 6 & B Ch 5

For Monday: see modern extensions of the Second Law:
The New Fluctuation Theorems

For Wednesday: see DS index for "Purpose in Life" (function)

HW Set# 28 Due W: DS # 6.47

HW Set# 29 Due F: DS # 7.6

HW Set# 30 Due M: DS # 7.11, 7.13

Oct. 24

Ever More Boltzmann Stats!
Ever More Boltzmann Factor!
Ever More Partition Function(!!)

Review

Oct. 26

EXAMINATION III covers through DS Ch 6

Review!

Oct. 28

Quantum Stats:
When and why is there a distinguishable difference?

DS Ch 7

The Brazil Nut Effect

HW Set# 31 Due W: B # 9.1, 9.20

HW Set# 32 Due F: B # 9.21

HW Set# 33 Due M: DS # 7.27

Oct. 31

Fermions & Bosons
at "Low" Temperatures

B Ch 8-9

Nov. 2

Consequences of having an Exclusion Principle (or not)

DS Sect. 7.3

Nov. 4

Semiconductor Physics

DS Sect. 7.3

Just READ each of the problems
on DS p. 297-300
Note the footnote on p. 300

HW Set# 34 Due W: DS # 7.35

HW Set# 35 Due F: DS # 7.41

HW Set# 36 Due M: DS # 7.65, 7.66

Nov. 7

Boson Physics
-- Special Case:
-- A Photon Gas (Thermal Radiation)

DS Sect. 7.4

Nov. 9

Phonons!
(Moving beyond Einstein Solids,
which assumed independent oscillators,
to the Debye Theory of Solids)

DS Sect. 7.5

Nov. 11

Another example of Summing over Modes:
Magnons! (Yet another effective quasiparticle of a many-body system)

DS Sect. 7.5

Laser Cooling of Atoms

HW Set# 37 Due W: Review!

HW Set# 38 Due F: DS # 7.67, 7.68

HW Set# 39 Due M: DS # 7.69

Nov. 14

Review

Pre-Quiz Materials

Nov. 16

EXAMINATION IV

Review!

Nov. 18

In the absense of an Exclusion Principle, we are allowed a Phase Transition into
a Novel State of Matter:
Bose-Einstein Condensation (BEC)

B Sect 9.4-9.6
DS Sect 7.6

Could there be a maximum temperature?

None

Nov. 21

Emerging from beyond the ideal gas approximation, ...

DS p. 327;
DS Sect. 8.2

Nov. 23

Thanksgiving Break

none

Nov. 25

Thanksgiving Break

none

None

HW Set# 40 Due W: DS # 7.70

HW Set# 41 Due F: DS # 7.71

Extra Credit ONLY:
DS # 8.28

Nov. 28

Mean Field Theory (MFT);
Monte Carlo Simulation

Finish reading DS

Nov. 30

Wrap-Up

Review final readings in DS

Dec. 2

EXAMINATION V

Exam Covers Massive Bosons, as well as Massless Bosons and Fermions

 

FINAL EXAMINATION: Thursday, Dec. 8, 8:00 - 10:00 am. It will be comprehensive.